CLEP Chemistry Free Sample Questions

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CLEP-CHEMISTRY Sample Questions

  1. Question 1

    Intermediate

    Structure of Matter · Atomic number and mass number; isotopes and mass spectroscopy

    Gallium has two naturally occurring stable isotopes: Ga-69 with an isotopic mass of 68.926 amu and Ga-71 with an isotopic mass of 70.925 amu. Given that the standard atomic weight of gallium reported on the periodic table is 69.723 amu, what is the natural percent abundance of the Ga-69 isotope?

    Answer and explanation

    Correct answer: B

    Solving 68.926(x) + 70.925(1 - x) = 69.723 yields -1.999x = -1.202, so x = 0.6013 (60.13% Ga-69).

  2. Question 2

    Intermediate

    Structure of Matter · Periodic relationships: ionization energies

    The successive molar ionization energies for an unknown representative element in Period 3 are determined experimentally as follows:

    • First ionization energy (IE1): 738 kJ/mol
    • Second ionization energy (IE2): 1,451 kJ/mol
    • Third ionization energy (IE3): 7,733 kJ/mol
    • Fourth ionization energy (IE4): 10,543 kJ/mol

    Based on these ionization energy values, which element is being evaluated?

    Answer and explanation

    Correct answer: D

    The sharp jump between IE2 and IE3 indicates removal of an inner core electron, confirming two valence electrons characteristic of Group 2 magnesium.

  3. Question 3

    Beginner

    Structure of Matter · Nuclear chemistry: nuclear equations, half-lives, and radioactivity

    In the radioactive decay series of uranium-238, a thorium-234 nucleus undergoes beta-minus (β⁻) emission to form an excited daughter nucleus of _____.

    Answer and explanation

    Correct answer: D

    Beta-minus decay increases atomic number Z by 1 (from 90 Th to 91 Pa) while leaving the mass number A unchanged at 234.

  4. Question 4

    Intermediate

    Structure of Matter · VSEPR theory and Lewis electron-dot diagrams

    According to valence shell electron pair repulsion (VSEPR) theory, what is the molecular geometry and the orbital hybridization of the central sulfur atom in sulfur tetrafluoride (SF4)?

    Answer and explanation

    Correct answer: A

    SF4 has 4 bonding pairs and 1 equatorial lone pair (steric number 5), yielding a trigonal bipyramidal electron geometry, seesaw shape, and sp3d hybridization.

  5. Question 5

    IntermediateMultiple answers

    Structure of Matter · Sigma and pi bonds

    Consider the bonding and molecular structure of acrylonitrile, H2C=CH-C≡N. Which TWO of the following statements correctly describe the covalent bonds and orbital hybridization in this molecule? (Select TWO)

    Answer and explanation

    Correct answers: B, D

    Counting single and multiple bonds: 3 C-H (σ) + 1 C=C (1σ, 1π) + 1 C-C (σ) + 1 C≡N (1σ, 2π) = 6 sigma and 3 pi bonds.

    The nitrogen forms one triple bond and retains one lone pair, yielding a steric number of 2 and linear sp hybridization.

  6. Question 6

    Beginner

    Structure of Matter · Binding forces: macromolecular (network) versus molecular

    True or False: Network covalent solids, such as silicon dioxide (SiO2) and diamond (C), exhibit substantially higher melting points than molecular solids, such as sucrose (C12H22O11) and dry ice (CO2), because melting network solids requires rupturing strong covalent bonds throughout the entire macroscopic lattice rather than disrupting relatively weak intermolecular forces.

    Answer and explanation

    Correct answer: A

    Melting network solids breaks primary covalent bonds extending in 3D, requiring far more thermal energy than overcoming intermolecular attractions.

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